Carbazole synthesis - Organic Chemistry Portal.
A new series of conjugated carbazole polymers based on the 1,8-carbazolylene unit was synthesized by the Pd-catalyzed polycondensation between the 1,8-diiodocarbazole derivative and various bifunctional counter comonomers. An alkyne spacer was found to be a key to increasing the molecular weight of the resulting polymers.
A Pd(II)-catalyzed C-H bond amination reaction operates under extremely mild conditions and produces carbazole products in good to excellent yields. Carbazoles possessing complex molecular architecture can also be formed using this reaction, highlighting its potential in natural product synthesis applications.
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Carbazole for synthesis Synonym: Carbazole, Diphenylenimine, 9-Azafluorene CAS Number 86-74-8. Empirical Formula (Hill Notation) C 12 H 9 N. Molecular Weight 167.21. EC Index Number 201-696-0.
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